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In possibly the biggest brandmance breakup in recent history, Victoria’s Secret announced Tuesday that its relationship with supermodel Gisele Bundchen “has reached a conclusion.”

RedEye takes a look at other celebrity-brand splits — and happy unions.

BREAKUPS

Whoopi Goldberg & Slim-Fast

Whoopi’s sexual puns on President Bush’s name at a John Kerry fundraiser were too much for Slim-Fast, which canned her as spokeswoman. She’s now hooked up with L.A. Weight Loss.

J.Lo & Louis Vuitton

The handbag maker dropped J.Lo from its ad campaign after just one year and instead recruited a bevy of supermodels — including Kate Moss and Naomi Campbell — to hawk its wares.

Kate Moss & Burberry, Chanel and H&M

Burberry, Chanel and H&M all severed ties with the supermodel after a London newspaper published photos that allegedly showed Moss snorting cocaine.

HOOKUPS

Fergie & Candies

The Black Eyed Peas singer is front and center in the footwear company’s spring ad campaign.

Drew Barrymore & CoverGirl

CoverGirl’s newest model and spokeswoman joins a crew of famous faces that includes Queen Latifah and Rihanna.

Mischa Barton & Keds

“The O.C.” actress has a three-year contract to be the face of Keds shoes around the world.